Tuesday, April 26, 2011

History of Periodic Table

In the Beginning
  • The first scientific discovery of an element occurred in 1649 when Hennig Brand discovered phosphorous.
    • By 1869, a total of 63 elements had been discovered.
    • As more and more elements were being discovered, scientists began to recognize patterns in properties.
  • In 1863, John Newlands arranged chemical elements in order of their relative atomic masses and he arranged his elements in columns.
  • John Newlands
    • He proposed the Law of Octaves in 1864
    • This law stated that any element will show similar behaviours at the eighth element following it in the table.

Dmitri Mendeleev
  • In 1864, Dmitri Mendeleev improved Newlands' idea and proved its effectiveness.
    • Mendeleev is known as the 'father' of the periodic table.
    • He organized the periodic table like no other chemist.
    • He managed to organize them into groups possessing similar properties, not by atomic mass.
    • He left gaps in the table, predicting that a new element would be discovered in place.
Mendeleev's Periodic Table

  • In 1895, Lord Rayleigh discovered the gaseous element Argon.
    • Did not fit with any of the periodic groups.
  • In 1898, William Ramsey organize argon into the periodic table between chlorine and potassium.
    • He made this decision even though argon's atomic weight was greater than potassium's.
    • This group was called "zero" group due to the zero number of valence electrons in each element.
    • He also predicted correctly properties such as neon.
    • This groups is currently called the Noble Gases.

Modern Periodic Table
  • Glenn Seaborg made the last major changes to the periodic table.
    • Discovered plutonium in 1940
    • Also discovered all elements from 94 to 102.
    • Reconfigured table by moving the actinide series below the lanthanide series.
    • Element 106 was name seaborgium (Sg) in his honor.
  • The periodic table is completely organized by atomic number not by mass.
  • Periodic Law: Elements recur periodically when arranged from lowest to highest atomic number.

Divisions in Periodic Table
  • Period: horizontal rows
  • Groups or Families: vertical columns
  • Blocks: according to subshells (s-, p-, d-, and f-block)
Periodic Table Blocks

Chemical Families
  • Alkali Metals
    • Group 1
    • Located in the s-block
    • Highly reactive metals
  • Alkaline Earth Metals
    • Group 2
    • Located in the s-block
    • Share similar properties
    • Relatively reactive metals
  • Halogens
    • Group 17
    • Non-metal elements
    • Contains all three familiar states of matter at a regular temperature and pressure.
    • Highly reactive because the atoms are highly electronegative due to heir high nuclear charge.
    • Reacts with water.
  • Noble Gases
    • Share similar properties
    • All odorless, colorless, monatomic gases, with low chemical reactivity.
    • Groups 18
    • Outer shell full
  • Lanthanide Series
    • Includes 15 elements with atomic number 57 through 71.
    • Are f-block elements
    • Lanthanum and lutetium are labeled group 3 because they both have a single valence electron, therefor in the d-shell.
  • Actinide Series
    • Includes 15 elements from 89 to 103.
    • Have similar properties.
    • f-block elements
    • Have a much more variable valence than the lanthanies.
    • All radioactive and release energy during radioactive decay
    • Can be used in nuclear reactors and nuclear weapons.
Modern Periodic Table

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